一、鋰電池
嚴格(ge)意義上說,鋰(li)電(dian)(dian)池(chi)(chi)(chi)分為兩種(zhong):鋰(li)金(jin)屬電(dian)(dian)池(chi)(chi)(chi)和鋰(li)離子電(dian)(dian)池(chi)(chi)(chi)。這是根據(ju)鋰(li)存(cun)在的形態來定義的,鋰(li)金(jin)屬電(dian)(dian)池(chi)(chi)(chi)是用金(jin)屬鋰(li)做電(dian)(dian)極,而鋰(li)離子電(dian)(dian)池(chi)(chi)(chi)則(ze)是以離子形態存(cun)在于電(dian)(dian)極。
鋰(li)(li)金屬(shu)(shu)電(dian)(dian)(dian)(dian)(dian)(dian)池(chi)通過金屬(shu)(shu)鋰(li)(li)的(de)腐蝕或叫氧化來產生電(dian)(dian)(dian)(dian)(dian)(dian)能(neng)的(de),用完就廢(fei)了,不能(neng)充電(dian)(dian)(dian)(dian)(dian)(dian),因此也稱(cheng)一次電(dian)(dian)(dian)(dian)(dian)(dian)池(chi)。鋰(li)(li)離(li)子(zi)電(dian)(dian)(dian)(dian)(dian)(dian)池(chi)則是利用鋰(li)(li)離(li)子(zi)的(de)濃度差(cha)進(jin)行儲能(neng)和放電(dian)(dian)(dian)(dian)(dian)(dian),電(dian)(dian)(dian)(dian)(dian)(dian)池(chi)中(zhong)不存在金屬(shu)(shu)鋰(li)(li),因此也稱(cheng)鋰(li)(li)二次電(dian)(dian)(dian)(dian)(dian)(dian)池(chi)。目前所應(ying)用于手機(ji)、相機(ji)、電(dian)(dian)(dian)(dian)(dian)(dian)動工具、電(dian)(dian)(dian)(dian)(dian)(dian)動汽車、儲能(neng)、通信基站等可充鋰(li)(li)電(dian)(dian)(dian)(dian)(dian)(dian)池(chi),均為(wei)鋰(li)(li)離(li)子(zi)電(dian)(dian)(dian)(dian)(dian)(dian)池(chi)。一般市場上大(da)多(duo)數(shu)常用可見的(de)鋰(li)(li)電(dian)(dian)(dian)(dian)(dian)(dian)池(chi)均為(wei)鋰(li)(li)離(li)子(zi)電(dian)(dian)(dian)(dian)(dian)(dian)池(chi),大(da)家也習慣簡稱(cheng)為(wei)鋰(li)(li)電(dian)(dian)(dian)(dian)(dian)(dian)池(chi),本文所稱(cheng)鋰(li)(li)電(dian)(dian)(dian)(dian)(dian)(dian)池(chi)也主(zhu)要指鋰(li)(li)離(li)子(zi)電(dian)(dian)(dian)(dian)(dian)(dian)池(chi)。
1、鋰電池分類
市場上習慣用的兩種分類(lei)方式:按極(ji)片材料分類(lei)和按產品外觀分類(lei)。
A、按極片材料分類
正極材料:磷酸鐵鋰(li)(li)(li)電池(chi)(chi)(LFP)、鈷酸鋰(li)(li)(li)電池(chi)(chi)(LCO)、錳(meng)(meng)酸鋰(li)(li)(li)電池(chi)(chi)(LMO)、(二元電池(chi)(chi):鎳錳(meng)(meng)酸鋰(li)(li)(li)/鎳鈷酸鋰(li)(li)(li))、(三元:鎳鈷錳(meng)(meng)酸鋰(li)(li)(li)電池(chi)(chi)(NCM)、鎳鈷鋁酸鋰(li)(li)(li)電池(chi)(chi)(NCA))
負(fu)極材料:鈦酸鋰電池(LTO)、石墨烯電池、納(na)米(mi)碳纖維電池
關(guan)于市場上(shang)(shang)的石墨(mo)烯(xi)(xi)(xi)概(gai)念,主要是指(zhi)石墨(mo)烯(xi)(xi)(xi)基電池,即在(zai)(zai)極片中加入石墨(mo)烯(xi)(xi)(xi)漿料(liao),或在(zai)(zai)隔(ge)膜上(shang)(shang)加入石墨(mo)烯(xi)(xi)(xi)涂層。鎳(nie)酸鋰、鎂(mei)基電池市場上(shang)(shang)基本不存(cun)在(zai)(zai)。
B、按產品外觀分類
分為:圓柱、軟(ruan)包、方形。
圓柱和方形外(wai)包裝多為鋼殼或者鋁(lv)殼。軟(ruan)包外(wai)包裝為鋁(lv)塑膜,其實軟(ruan)包也(ye)是一種方形,市(shi)場(chang)上習慣將鋁(lv)塑膜包裝的(de)稱(cheng)為軟(ruan)包,也(ye)有人(ren)將軟(ruan)包電(dian)池(chi)稱(cheng)為聚(ju)合物(wu)電(dian)池(chi)。
對(dui)于圓(yuan)柱形鋰離子電(dian)池,其型號一(yi)般(ban)為(wei)(wei)(wei)5位(wei)數(shu)字(zi)。前兩位(wei)數(shu)字(zi)為(wei)(wei)(wei)電(dian)池的直徑,中(zhong)間兩位(wei)數(shu)字(zi)為(wei)(wei)(wei)電(dian)池的高(gao)度(du)。單位(wei)為(wei)(wei)(wei)毫米(mi)。例(li)如18650鋰電(dian)池,它(ta)的直徑為(wei)(wei)(wei)18毫米(mi),高(gao)度(du)為(wei)(wei)(wei)65毫米(mi)。
C、按電解質材料的不同
鋰(li)離(li)子電(dian)池分為液態鋰(li)離(li)子電(dian)池(LIB)和聚合物鋰(li)離(li)子電(dian)池(PLB)。
液態鋰離(li)子(zi)電(dian)(dian)(dian)(dian)(dian)池(chi)使(shi)用(yong)(yong)液體(ti)電(dian)(dian)(dian)(dian)(dian)解(jie)質(zhi)(目前動(dong)力用(yong)(yong)電(dian)(dian)(dian)(dian)(dian)池(chi)多為此(ci)種)。聚合(he)物鋰離(li)子(zi)電(dian)(dian)(dian)(dian)(dian)池(chi)則以固體(ti)聚合(he)物電(dian)(dian)(dian)(dian)(dian)解(jie)質(zhi)來代替,這種聚合(he)物可(ke)以是“干態”的,也可(ke)以是“膠(jiao)態”的,目前大部分采(cai)用(yong)(yong)聚合(he)物凝膠(jiao)電(dian)(dian)(dian)(dian)(dian)解(jie)質(zhi)。關(guan)于固態電(dian)(dian)(dian)(dian)(dian)池(chi),嚴格(ge)意義上的是指電(dian)(dian)(dian)(dian)(dian)極和電(dian)(dian)(dian)(dian)(dian)解(jie)質(zhi)均為固態的。
D、按電池實用性能分類
功率(lv)(lv)型電池(chi)(chi)和能(neng)量型電池(chi)(chi)。能(neng)量型電池(chi)(chi)以(yi)高(gao)(gao)能(neng)量密度為特點,主(zhu)要(yao)用于(yu)高(gao)(gao)能(neng)量輸(shu)(shu)出(chu)(chu)(chu);功率(lv)(lv)型電池(chi)(chi)以(yi)高(gao)(gao)功率(lv)(lv)密度為特點,主(zhu)要(yao)用于(yu)瞬間高(gao)(gao)功率(lv)(lv)輸(shu)(shu)出(chu)(chu)(chu)、輸(shu)(shu)出(chu)(chu)(chu)的電池(chi)(chi)。而(er)功率(lv)(lv)能(neng)量型鋰電池(chi)(chi)是伴隨著插(cha)電式混合動(dong)力(li)車的出(chu)(chu)(chu)現而(er)出(chu)(chu)(chu)現的。它要(yao)求電池(chi)(chi)儲存(cun)的能(neng)量較高(gao)(gao),可以(yi)支持一段距離的純電行駛(shi),也(ye)要(yao)具備較好的功率(lv)(lv)特性(xing),在低(di)電量的時(shi)候(hou)進入混合動(dong)力(li)模式。
簡單理解,能量型類(lei)似于馬拉(la)松選手(shou),要有耐力,就是(shi)要求(qiu)高容量,對(dui)大電流放電性能要求(qiu)不高;那么功率型就是(shi)短(duan)跑選手(shou),拼的(de)是(shi)暴發力,但耐力也要有,不然容量太小就跑不遠。
2、鋰電池材料構成

四大主材:正極材料、負極材料、隔膜(mo)、電(dian)解液
輔材:NMP、銅箔、鋁箔、鋁殼(ke)蓋板、導(dao)電劑、粘結劑、其他(ta)(EMD)等。
3、制作工藝
鋰電池的制造流程可分為電極制片(pian)、電芯裝(zhuang)(zhuang)配、激活檢測和電池組裝(zhuang)(zhuang)四個(ge)主(zhu)要工(gong)序。其中,電極制片(pian)又包括正極片(pian)和負極片(pian)制作,主(zhu)要環(huan)節包括配料、攪拌、涂布、輥壓(ya)、分切和極耳(er)等步驟(zou)。

4、生產所需設備
按照(zhao)鋰離子電池的生產流程,鋰電設(she)備主要可(ke)以分(fen)為前端(duan)設(she)備、中端(duan)設(she)備和后端(duan)設(she)備。
前(qian)(qian)端(duan)設備(bei)主要是(shi)(shi)針對電(dian)極制片(pian)(pian)工序,包(bao)括真空(kong)攪(jiao)拌機、涂布機、輥壓機和分(fen)切機等。涂布工藝要求(qiu)將(jiang)攪(jiao)拌后的(de)漿料(liao)均勻(yun)地涂在(zai)金(jin)屬上,厚(hou)度精確(que)到3μm以下,分(fen)切要需要保證切片(pian)(pian)表面不能(neng)存(cun)在(zai)任何毛刺,否則(ze)會對后續工藝產生很大影響。因此,前(qian)(qian)端(duan)設備(bei)是(shi)(shi)電(dian)池制造的(de)核心設備(bei),關乎整條(tiao)生產線的(de)質量(liang)。
中端設(she)備主(zhu)要覆(fu)蓋電芯裝(zhuang)配工(gong)序,主(zhu)要包括卷繞機(ji)或疊片機(ji)、電芯入殼機(ji)、注(zhu)液機(ji)以及(ji)封口(kou)焊(han)接等設(she)備。
后(hou)端設備(bei)主要(yao)覆蓋(gai)電芯激(ji)活化成、分容檢測以及組裝成電池組等(deng)工藝。相對而言,中后(hou)端設備(bei)如入殼、封口、檢測等(deng)機器相對簡單,技術(shu)要(yao)求(qiu)不高。

5、鋰電池應用
主要分為三大塊:數碼類(lei)、動力類(lei)、儲能(neng)類(lei)。
數碼類(lei):手機(ji)、平板、筆記本(ben)電腦(nao)、電動玩(wan)具(ju)、MP3/MP4、耳機(ji)、充電寶(bao)、航模(mo)、移(yi)動電源等。
動(dong)力(li)類(lei):主要指電動(dong)交(jiao)通工具,電動(dong)自行車(che)、新能(neng)源汽車(che)等。
儲能(neng)(neng)類:主(zhu)要應用(yong)于(yu)基站電源、清潔能(neng)(neng)源儲能(neng)(neng)、電網電力儲能(neng)(neng)、家(jia)庭(ting)光儲系統等。
6、鋰電池相關參數及發展方向
